Cation exchange in soil.
Clay soils are usually alkaline and bind positively charged minerals (cations such as Ca^2+).
Hydrogen ions (H^+) help make nutrients available by displacing the cations.
Plants secreting H^+ by cellular respiration: CO[2] reacts with H[2]O to form carbonic acid (H[2]CO3) in the soil, which dissociates to add H^+ to the soil.